doi.org/10.1063/5.0182…

Freshly published, another 103Rh NMR paper - this time exotic! Rh-Rh J-couplings, 18O secondary isotope shifts and the first ever reported 103Rh Singlet State (This is the Levitt Research Group after all!)

Mohamed Sabba Markus L.

JUST PUBLISHED: Harry Harbor-Collins's first paper; a step towards making rhodium NMR fast and accessible. Another fun collaboration with Markus L.!

pubs.aip.org/aip/jcp/articl…

This is a very impressive NMR setup - I was a postdoc at MRRC Cambridge back when the whole setup was installed and it’s nice to see where it end up - I recommend reading the paper 😀

What an interesting & initially puzzling project to be part of. Thanks to the whole team, but especially Yue Pang.

How does the reductive elimination of aryl-F from Bi(V) work?🤔

Check out my last dance with Cornellab, a HUGE study that includes kinetics, DFT, 23 (!) X-ray structures and improved stoichiometric and catalytic methodologies to furnish fluoroarenes!

pubs.acs.org/doi/10.1021/ja…

#nmrchat

Hydrogenative Cycloisomerization and Sigmatropic Rearrangement Reactions of Cationic Ruthenium Carbenes Formed by Catalytic Alkyne gem-Hydrogenation (Fuerstner) Max Planck Society #OpenAccess thanks to #ProjektDEAL onlinelibrary.wiley.com/doi/10.1002/an…

Congratulations to Ben List and all the new and former colleagues from AK List 🥳🥳🥳

Reporting in J. Am. Chem. Soc.: low-valent Bi redox catalysis via elementary organometallic steps: catalytic hydrodefluorination. Excellent work by Yue (@YPYuePang) Markus (@MrIrieman), Nils and Felix! pubs.acs.org/doi/10.1021/ja…

Happy to share a new triple resonance approach for the detection of #103Rh #NMR Shifts together with my colleagues from #MPIKofo pubs.acs.org/doi/10.1021/ja…

Yet another collaboration with the colleagues from the Fürstner and Neese groups at #MPIKofo . This time we report more detailed mechanistic insights into alkyne metathesis with the 'Canopy Catalysts'. pubs.acs.org/doi/10.1021/ja…

This trans-hydrogenation reaction and PHIP studies on it was a part of my PhD work. It’s great to see such advances on that 👍

The next collaboration with my colleagues from the Fürstner group: This time we report how [Cp*RuCl]4 can catalyze trans-hydro- and trans-chloroalkynylations of internal alkynes and give some mechanistic insights from X-Ray structures and NMR studies.
pubs.acs.org/doi/10.1021/ja…

It’s great seeing it finally online 🙂 It was a pleasure being part of the team 👌

Another chapter in the recent work on Alkyne metathesis together with the #FürstnerLab and Copéret Group. This time we managed to use the cinderella nucleus 183W to guide our studies.

Another nice collaboration with my colleagues from AK List

Finally Online 🙃 Together with my colleagues from the Fürstner group we today report some new advances for alkyne metathesis. The work also includes some 95Mo #NMR studies and great insights from DFT-based chemical shift tensor analysis by Copéret Group pubs.acs.org/doi/10.1021/ja…

Setting up some #NMR measurements from home thanks to VPN and remote access to my office computer. Thanks to the IT Department and my colleagues at #MPIKofo for making this possible ❤️ Max Planck Society #Homeoffice #NMR chat

Thanks Cornellab Oriol Planas having me in your team for this fascinating project 👌

Great work together with my colleagues from AK List.