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메커니즘 - 2
Hydrolysis of intermediate

OH-가 Mn을 어택하고, O가 떨어져나간다
그 다음, H2O가 카본의 O-를 protonate 한다

위 프로세스가 두번 일어남

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브뢴스테드 약산 (pKa>5)은 강산(pKa<5)이 촉매로 작용할때 C=C와 addition을 할 수 있다
이 반응은 3 스텝으로 이루어진다

1. 강산이 약산을 protonate시켜서 약산의 Conjugate acid를 만들고, 그 Conjugate acid가 C=C를 protonate 시킴 (강산과 동일)

Friedel-Crafts Reactions

Carbocation을 electrophile로 사용하는 EAS

C+는
pi 본드를 protonate 하거나
carbon-LG를 ionize 해서 만들 수 있다는거 기억하기

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Hello, I have an issue when I want to protonate some ligands, it send me this error and I don't know what to do. CCG_MOE

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“list of mechanisms: 1. cyanohydrins (start with ketone + HCN, goes by strong mechanism - attack, protonate)” was found in my notes

Wait I kinda understand wolff kishner you just protonate everythung until it falls off and for the N2 formation you just deprotonate it over and over

Here, taking an informed approach based on GFP chemistry allowed us to flip the ASAP response while improving performance: Shifting the location of a H-bond donor by 1aa allows depolarization-induced motions to deprotonate (brighten) the chromophore rather than protonate it.

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We’ve spent a lot of time trying to develop stronger reductants in my group but none of those systems were effective on their own. The trick to enabling this new deoxygenation reaction was working out that acids can protonate radical anion intermediates and promote C–O scission.

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